Drag a state into each circle. The arrow reads from the first circle to the second.
On a phone or tablet, tap a state and then tap a circle.
→changes to
Your resultChoose two states to begin
The direction matters: solid → liquid is melting, but liquid → solid is freezing.
Solid: ordered Liquid: close, irregular Gas: far apart
IGCSE · Electrolysis and metal extraction
Extracting aluminium by electrolysis
Watch ions move through molten aluminium oxide dissolved in cryolite. The graphite lining is the negative cathode; the carbon blocks are positive anodes.
1Break crust & feed Al₂O₃
2Dissolve in cryolite
3Electrolyse at ≈960°C
4Form CO₂ & consume carbon
5Tap molten aluminium
−DC supply+
Drag to rotate · scroll or pinch to zoom · right-drag to pan
Al³⁺O²⁻electronCO₂
Ready
Before electrolysis: the Bayer process purifies bauxite into alumina, Al₂O₃.Cryolite dissolves alumina and lowers the operating temperature to about 960°C.Cell polarity: the carbon lining is the cathode; suspended carbon blocks are the anodes.Overall: 2Al₂O₃ + 3C → 4Al + 3CO₂
Kp Simulator
N₂O₄ ⇌ 2 NO₂ · Endothermic (ΔH° = +57.2 kJ/mol)
Only temperature changes Kp. Changing pressure (volume) or concentration shifts the
equilibrium position but the Kp calculation always gives the same answer.
N2O4⇌2 NO2
🌡
Temperaturechanges Kp
298 K
📦
VolumeKp unchanged ✓
30.0 L
⚗
Initial N2O4Kp unchanged ✓
1.00 mol
Equilibrium gas mixture — mole fraction (bar width) shifts with volume & concentration; Kp computed below stays constant
N2O4colorless
NO2brown
Live Kp derivation — updates with every slider move
Drag the sliders — only temperature changes Kp; volume and concentration just shift the equilibrium position.
Electron Orbital Viewer
Point cloud weighted by |ψ(r)|² — denser regions have higher electron probability.
Hydrogen atom s-orbitals (a₀ = 1). Drag to rotate · scroll to zoom.
drag to rotate · scroll to zoom
1s orbital — lowest-energy state, spherically symmetric. Electron density peaks at the nucleus and decays exponentially outward. No radial nodes.
Electron Configuration Builder
Add electrons one at a time · Aufbau principle · Hund's rule applied within each sublevel
Covers elements H → Zn (Z = 1–30) · 4s fills before 3d per Aufbau order
—Z = 0
0 / 30 electrons
Electron Configuration
—
Chromium & Copper: Aufbau Exceptions
Cr (Z=24) and Cu (Z=29) deviate from the Aufbau principle because
half-filled and fully-filled d subshells are extra stable.
Cr
Chromium Z = 24
Group 6 · Period 4 · [Ar] core = 1s² 2s² 2p⁶ 3s² 3p⁶
Aufbau predicts
[Ar] 4s² 3d⁴
4s
↑↓
3d
↑
↑
↑
↑
→
Actual
[Ar] 4s¹ 3d⁵
4s
↑
3d
↑
↑
↑
↑
↑
⚡
The 3d subshell is half-filled (3d⁵ — one electron per orbital, all spin-up).
This maximises exchange energy and minimises electron-electron repulsion, making
4s¹ 3d⁵ lower in energy than the predicted 4s² 3d⁴.
One electron is effectively "promoted" from 4s into the empty 3d orbital.
Cu
Copper Z = 29
Group 11 · Period 4 · [Ar] core = 1s² 2s² 2p⁶ 3s² 3p⁶
Aufbau predicts
[Ar] 4s² 3d⁹
4s
↑↓
3d
↑↓
↑↓
↑↓
↑↓
↑
→
Actual
[Ar] 4s¹ 3d¹⁰
4s
↑
3d
↑↓
↑↓
↑↓
↑↓
↑↓
⚡
The 3d subshell is fully filled (3d¹⁰).
A completely filled d subshell is particularly stable.
The atom reaches it by promoting one 4s electron into the last 3d orbital,
giving 4s¹ 3d¹⁰ instead of the predicted 4s² 3d⁹.
Key takeaway
Both exceptions involve a one-electron shift from 4s → 3d to achieve an
especially stable d subshell (half-filled 3d⁵ for Cr, fully-filled 3d¹⁰ for Cu).
The same pattern recurs across the periodic table: Mo (Z=42), Ag (Z=47), Au (Z=79),
and others. These exceptions are a frequent exam topic in AP, IB, and university chemistry.
Interactive Atomic Model
Oxygen-16 · 8 protons · 8 neutrons · 8 electrons · click any particle to inspect it
8O15.999
Shell 12e⁻Shell 26e⁻
Drag to turn · click a particle · click empty space for element info